ASA

Here you can find the MSDS for the fabWeaver ASA filament.

Here is the info on MSDS of fabWeaver ASA filament.

Please download fabWeaver ASA filament MSDS link for the full specs.

SAFETY DATA SHEET


1. Identification of the substance or mixture and of the supplier

A. GHS product identifier : ASA

B. Recommended use of the chemical and restrictions on use
    Recommended use : 3D Printing Filament
    Restrictions on use : Use for recommended use only

C. Supplier
    Company name : Sindoh Co. Ltd. (brand name : fabWeaver)
    Address : Seongsui-ro 24-gil, Seongdong-gu, Seoul, Republic of Korea
    Emergency phone number : +82-1588-5850
    Respondent : +82-2-460-1114
    Fax : +82-2-466-0205

 

2. Hazards identification

A. GHS classification of the substance/mixture
     Not classified

B. GHS label elements, including precautionary statements
     Pictogram and symbol : Not applicable
     Signal word : Not applicable
     Hazard statements : Not applicable
     Precautionary statements
          Precaution : Not applicable
          Treatment : Not applicable
          Storage : Not applicable
          Disposal : Not applicable

C. GHS label elements, including precautionary statements : Not available

 

3. Composition/information on ingredients 

Chemical Name

Common Name
(Synonyms)

CAS number  EC number  Content (%)

2-Methyl-2-propenoic acid methyl ester polymer with butyl 2-propenoate,
ethenylbenzene and 2-propenenitrile  

Titanium dioxide

Acrylonitrile Styrene Acrylate Copolymer

 

-

25852-38-4

 

13463-67-7

-

 

236-675-5

97-100

 

< 1

 

4. First aid measures

A. Eye contact
    - In case of contact with substance, immediately flush eyes with running water for at least
      20 minutes.
    - Get immediate medical advice/attention.
    - If eye irritation persists: Get medical advice/attention.
    - Call a POISON CENTER/doctor/etc if you feel unwell.

B. Skin contact
    - In case of contact with substance, immediately flush skin with running water for at least
      20 minutes.
    - Remove and isolate contaminated clothing and shoes.
    - Wash contaminated clothing and shoes before reuse.
    - If skin irritation occurs: Get medical advice/attention.
    - Call a POISON CENTER/doctor/etc if you feel unwell.

C. Inhalation
    - Remove victim to fresh air and keep at rest in a position comfortable for breathing.
    - Give artificial respiration if victim is not breathing.
    - Administer oxygen if breathing is difficult.
    - Specific medical treatment is urgent.
    - Keep victim warm and quiet.
    - Call a POISON CENTER/doctor/etc if you feel unwell.

D. Ingestion
    - Do not let him/her eat anything, if unconscious.
    - Get immediate medical advice/attention.
    - Call a POISON CENTER/doctor/etc if you feel unwell.

E. Indication of immediate medical attention and notes for physician
    - Ensure that medical personnel are aware of the material(s) involved and take
      precautions to protect themselves.

 

5. Fire fighting measures

A. Suitable (and unsuitable) extinguishing media 
    - Suitable extinguishing media: Dry sand, dry chemical, alcohol-resistant foam, water
      spray, regular foam, CO2
    - Unsuitable extinguishing media: High pressure water streams

B. Specific hazards arising from the chemical
    - May be ignited by heat, sparks or flames.
    - Fire may produce irritating and/or toxic gases.
    - Inhalation of material may be harmful.
    - Some liquids produce vapors that may cause dizziness or suffocation.

C. Special protective equipment and precautions for fire-fighters
    - Move containers from fire area if you can do it without risk.
    - Some may be transported hot.
    - Runoff from fire control or dilution water may cause pollution.
    - Contact may cause burns to skin and eyes.
    - Dike fire-control water for later disposal; do not scatter the material.
    - In case or fire: Use personal protective equipment as required.
    - Fire fighters should put on appropriate protective gear and self-contained breathing
      apparatus.
    - Fire may produce oxocarbons.

 

6. Accidental release measures

A. Personal precautions, protective equipment and emergency procedures
    - Eliminate all ignition sources.
    - Stop leak if you can do it without risk.
    - Please note that materials and conditions to avoid.
    - Ventilate the area.
    - Do not touch or walk through spilled material.
    - Prevent dust cloud.
    - Spills and leaks: Use personal protective equipment as required.
    - Evacuate personnel and unprotected persons to safe areas.

B. Environmental precautions and protective procedures
    - Prevent entry into waterways, sewers, basements or confined areas.

C. The methods of purification and removal
    - Collect spillage.
    - Small Spill; Flush area with flooding quantities of water.
    - With clean shovel place material into clean, dry container and cover loosely; move
      containers from spill area.
    - Powder Spill; Cover powder spill with plastic sheet or tarp to minimize spreading and
      keep powder dry.

 

7. Handling and storage

A. Precautions for safe handling
    - Please note that materials and conditions to avoid.
    - Please work with reference to engineering controls and personal protective equipment.
    - Be careful to high temperature.
    - Do not handle until all safety precautions have been read and understood. 
    - Wash the handling area thoroughly after handling.
    - Do not eat, drink or smoke when using this product.
    - Use carefully in handling/storage.

B. Conditions for safe storage
    - Store in a closed container.
    - Store in cool and dry place.
    - Store locked up.
    - Keep away from food and drinking water.
    - Store in a well-ventilated place.
    - Containers which are opened must be carefully resealed and kept upright to prevent
      leakage.

 

8. Exposure controls/personal protection

A. Occupational Exposure limits
    OSHA regulation :
        - Titanium dioxide : TWA = 15 mg/m³
    NIOSH regulation :
        - Titanium dioxide : NIOSH Potential Occupational Carcinogens
    ACGIH regulation :
        - Titanium dioxide : TWA = 10 mg/m³
    EU regulation : Not applicable
    Biological exposure index : Not available

B. Appropriate engineering controls
    - Provide local exhaust ventilation system or other engineering controls to keep the
      airborne concentrations of vapors below their respective threshold limit value.

C. Personal protective equipment
    Respiratory protection :
        - Wear NIOSH or European Standard EN 149 approved full or half face piece (with
goggles) respiratory protective equipment when necessary.
        - In case exposed to gaseous/liquid material, the respiratory protective equipments as
follow are recommended.
        - facepiece filtering respirator or air-putifying respirator, high-efficiency particulate
air(HEPA) filter media or respirator equipped with powered fan, filter media of use(dust,
mist, fume)
        - In lack of oxygen(< 19.6%), wear the supplied-air respirator or self-contained
breathing apparatus.
    Eye protection :
        - Wear breathable safety goggles to protect from particulate material causing eye
irritation or other disorder.
        - An eye wash unit and safety shower station should be available nearby work place.
    Hand protection :
        - Wear appropriate protective gloves by considering physical and chemical properties of chemicals.
        - Wear gloves when handling hot/molten material.
    Body protection : 
        - Wear appropriate protective clothing by considering physical and chemical properties of chemicals.

 

9. Physical and chemical properties

A. Appearance
    Description : Solid
    Color : Milky

B. Odor : Odorless

C. Odor threshold : Not available

D. pH : Not available

E. Melting point/freezing point : Not available

F. Initial boiling point and boiling range : Not available

G. Flash point : Not available

H. Evaporation rate : Not available

I. Flammability (solid, gas) : Not available

J. Upper/lower flammability or explosive limits : Not available

K. Vapor pressure : Not available

L. Solubility (ies) : Not available (Insoluble)

M. Vapor density : Not available

N. Specific gravity : 1.07

O. Partition coefficient: n-octanol/water : Not available

P. Auto ignition temperature : Not available

Q. Decomposition temperature : Not available

R. Viscosity : Not applicable

S. Molecular weight : Not available

 

10. Stability and reactivity

A. Chemical stability and Possibility of hazardous reactions
    - Fire may produce irritating and/or toxic gases.
    - Inhalation of material may be harmful.
    - Some liquids produce vapors that may cause dizziness or suffocation.

B. Conditions to avoid
    - Ignition sources (heat, sparks or flames)

C. Incompatible materials
    - Flammable material
    - Strong oxidizing agents.

D. Hazardous decomposition products
    - Irritating and/or toxic gases
    - Oxocarbons

 

11. Toxicological information

A. Information of Health Hazardous
    Acute toxicity
        Oral : Not available
        Dermal : Not available
        Inhalation : Not available
    Skin corrosion/ irritation : Not available
    Serious eye damage/ irritation : Not available
    Respiratory sensitization : Not available
    Skin sensitization : Not available
    Carcinogenicity : Not classified
            - 2-Methyl-2-propenoic acid methyl ester polymer with butyl 2-propenoate,
            ethenylbenzene and 2-propenenitrile :
                        - IARC, ACGIH, OSHA, NTP, EU CLP: Not listed
            - Titanium dioxide :
                     IARC: Group 2B
                    ACGIH: A4
                    OSHA: Present
                    EU CLP: Carc. 2 (in powder form containing 1 % or more of particles with         
                    aerodynamic diameter ≤ 10 μm)
                      - NTP: Not listed
    Mutagenicity : Not available
    Reproductive toxicity : Not available
    Specific target organ toxicity (single exposure) : Not available
    Specific target organ toxicity (repeat exposure) : Not available
    Aspiration Hazard : Not available